Low Field NMR Research on Rubber Crosslinking Density

Low Field NMR Research on Crosslinking Density

Crosslinking Density of Rubber

The degree of cross-link, also known as the crosslinking density, is usually expressed in terms of cross-link density or the number-average molecular weight between two adjacent cross-link points or the number of moles of cross-link points per cubic centimeter. The rubber with a small degree of crosslinking has better elasticity, while the rubber with a large degree of crosslinking has poor elasticity. If the degree of crosslinking increases, the mechanical strength and hardness will increase, and eventually the elasticity will be lost.

The degree of rubber crosslinking has always been a problem in the industry. The traditional swelling method has low test accuracy and is subject to large human subjective factors. In the NMR method, the polymer relaxation decay curve changes with the change of the state of the internal components of the sample, and the cross-linked and non-cross-linked chain signals can be quickly and non-destructively obtained by NMR relaxation technology to obtain the degree of crosslinking.

The solvent part in the polymer has strong fluidity and slow decay; the non-cross-linked segment has certain molecular motion characteristics, and the decay is relatively slow; while the cross-linked segment is bound to a large degree, the molecular motion characteristics are small, and the decay is faster. Compared with the traditional SE or CPMG sequence acquisition, when using the new MSE-CPMG sequence acquisition, the NMR signal is reversed back and forth within the dead time range by applying combined pulses, so as to maintain the original NMR signal intensity as much as possible. The shorter relaxation information is collected, and the test accuracy of the crosslinking density is further improved.

Low Field NMR Study on Rubber Crosslinking

Low field NMR analysis technology uses pulses to excite hydrogen protons in material samples to resonate, and after the pulse is stopped, hydrogen protons relax. The relaxation times of hydrogen protons in different states in the sample are different. The detection and analysis of the low field nmr relaxation signal can directly or indirectly detect some properties of the material. The low field NMR method uses low field nmr analysis technology to evaluate the movement of H molecules on the hydrocarbon chain and analyze the crosslinking degree of the sample according to the relaxation analysis model. The test process does not require chemicals, no es destructivo para la muestra, and the test speed is fast. Generalmente, the test can be completed within 3 minutos.

Low field NMR Analyzer Composition

The NMR crosslinking density meter usually consists of the following parts,
Control unit (control core, interface for human-computer interaction),
Magnet unit (the part that generates the radio frequency excitation and collects the signal),

In addition to the above parts, there are temperature control, power module, etc..